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Nanoporous Intermetallic Compounds That Boost Hydrogen Production
Hydrogen has the highest energy density (120 MJ/kg) of all known substances, approximately three times more than diesel or gasoline, meaning it could play a pivotal role in sustainable energy systems. But the efficient production of hydrogen by simple water splitting requires highly performing catalysts.
Now, a collaborative group from Tohoku University and Johns Hopkins University have developed nanoporous molybdenum-based intermetallic compounds that could boost hydrogen production.
Intermetallic compounds in nano-scale formed from non-precious transition metals have the potential to be cost-effective and robust catalysts for hydrogen production. However, the development of monolithic intermetallic compounds, with ample active sites and sufficient electrocatalytic activity, remains a challenge for scientists.
"Our research has played a crucial part in addressing that problem," says Professor Hidemi Kato, from the Institute for Materials Research at Tohoku University and co-author of the study. "Focusing on design and engineering, we harnessed an advanced dealloying technique for constructing the intermetallic compounds' architecture."
Liquid metal dealloying is a processing technique that utilizes the difference in alloy components' miscibility in a molten metal bath to corrode selected component(s), while retaining the others. It allows for self-organizing into a three-dimensional porous structure.
Furthermore, it enables the pore size to be controlled at the nanometer scale for both μ-Co7Mo6 and μ-Fe7Mo6, which are generally at the micrometer scale for the other metals/alloys when coarsening takes place at equivalent temperatures.
The principle and self-organizing process of liquid metal dealloying. In the precursor alloy (AB), the pore-forming metal (A) and sacrificial component (B) should have a positive and negative enthalpy when mixing with the melt bath (C), respectively. With the component B selectively dissolving into C melt, the remaining component A self-organizes into a porous structure. ©Takeshi Wada and Ruirui Song
The collaborative group then researched the electrocatalytic performance of the new nanoporous intermetallic compounds. It showed promise and potential for use as a commercial HER catalyst for high-current applications.
The results of their research were published in the journal Nature Communications on September 2, 2022.
In addition to Kato, the group comprised Dr. Ruirui Song, also from the Institute for Materials Research at Tohoku University, graduated from Graduate School of Engineering, Assistant Professor Jiuhui Han from the Frontier Research Institute for Interdisciplinary Sciences (FRIS) at Tohoku University and Professor Mingwei Chen from Johns Hopkins University.
Looking ahead, the research group hopes to use liquid metal dealloying to develop more monolithic nanoporous intermetallic compounds by exploring the fundamental mechanisms behind general intermetallic phases.
Title: Ultrafine nanoporous intermetallic catalysts by high-temperature liquid metal dealloying for electrochemical hydrogen production
Authors: Ruirui Song, Jiuhui Han, Masayuki Okugawa, Rodion Belosludov, Takeshi Wada, Jing Jiang, Daixiu Wei, Akira Kudo, Yuan Tian, Mingwei Chen & Hidemi Kato
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School of Engineering, Tohoku University